Suppliments for bodybuilding are pretty much a scam. There appears to be only 3 substances that seem to have been both well tested and have the majority of studies providing some limited positive feedback for bodybuilding enhancements:
1. Creatine Monohydrate - seems to enhance the muscles by providing them the ability to store extra water as well as providing you more energy for workouts.
2. Beta-alanine - may have a positive muscle building effect, but only in combination with creatine monohydrate. they should be taken together.
3. Caffeine - gives you more enery for a longer workout.
Everything else on the market, either doesn't have any good science behind it, or the science is pretty negative. Even for those 3 substances I listed the science is not unequivocal. Of the 3, the creatine seems to be the most useful and is relatively inexpensive as the dosage level is relatively low.
But bottom line is don't expect any legal suppliment to be of much use really. Just workout hard, get plenty of rest, and eat well (in that order) and you'll get the results your body is capable of.
BTW you can read this 2014 study for bodybuilding's latest nutrition info:
http://www.ncbi.nlm.nih.gov/pmc/article ... -11-20.pdf(I definitely don't agree with all the nutritional aspects in the study, but it is what it is)